Novel Synthesis of Dienones and Enones from Propargyl Alcohols and Allyl Alcohols with 2, 2-Dimethoxypropane: Synthesis of Ionone and Irone

Toshinobu ISHIHARA; Takeshi KITAHARA; Masanao MATSUI

doi:10.1271/bbb1961.38.439

Agricultural and Biological Chemistry

Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369

Novel Synthesis of Dienones and Enones from Propargyl Alcohols and Allyl Alcohols with 2, 2-Dimethoxypropane: Synthesis of Ionone and Irone

Toshinobu ISHIHARA, Takeshi KITAHARA, Masanao MATSUI

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ジャーナルフリー

1974 年 38 巻 2 号 p. 439-442

DOI https://doi.org/10.1271/bbb1961.38.439

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抄録

A new synthetic procedure for dienone derivatives, i.e., ionone and irone, is described. The key step is the pyrolytic rearrangement of allyl alcohols and 2, 2-dimethoxypropane in the presence of an acid anhydride and phosphoric acid.

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前身誌

Bulletin of the Agricultural Chemical Society of Japan

後続誌

Bioscience, Biotechnology, and Biochemistry

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