Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Biosynthesis of Epoxydon and Related Compounds by Phyllosticta sp.
Kensuke NABETAAkitami ICHIHARASadao SAKAMURA
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1975 年 39 巻 2 号 p. 409-413

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The tetraketide origin of epoxydon I produced by Phyllosticta sp. is established by 13C NMR measurement on labelled epoxydons obtained from 1-13C- and 2-13C-acetate. The chlorinating mechanism of epoxydon to form non-enzymatically compound IV, V and VI was also confirmed by exposing epoxydon to the culture broth.
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