Magnets for this Millennium Based Upon Coordination Compounds and New Coordination Chemistry

抄録

Numerous coordination compounds have recently been identified exhibit the technologically important property of bulk magnetic ordering as ferro-, ferri- and antiferromagnets. These compounds range from the ionic [Fe(C₅Me₅)₂]⁺[TCNE]^.- (TCNE = tetracyanoethylene) ferromagnet to 3-D extended coordination network ferrimagnets. Additionally, many magnetically ordered percyanometallates are summarized. This Award presentation covers new magnetically ordered coordination compounds with an emphasis on new coordination chemistry that were discovered and studied in our laboratory.