First Synthesis of (+)-α- and (+)-γ-Polypodatetraenes

Masako Kinoshita; Mahisa Ohtsuka; Daisuke Nakamura; Hiroyuki Akita

doi:10.1248/cpb.50.930

Regular Articles

First Synthesis of (+)-α- and (+)-γ-Polypodatetraenes

Masako Kinoshita, Mahisa Ohtsuka, Daisuke Nakamura, Hiroyuki Akita

著者情報

キーワード: (+)-α-polypodatetraene, (+)-γ-polypodatetraene, total synthesis

ジャーナルフリー

2002 年 50 巻 7 号 p. 930-934

DOI https://doi.org/10.1248/cpb.50.930

詳細

抄録

First synthesis of (+)-α-polypodatetraene (1) and (+)-γ-polypodatetraene (2) was achieved from (+)-albicanol (6) and (−)-drimenol (8), respectively. The absolute structure of natural (+)-2 was established to be (5S,9S,10S)-polypoda-7,13(E),17(E),21-tetraene.

責任著者(Corresponding author)

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