2004 年 52 巻 3 号 p. 354-358
Three new diterpenes, sugikurojins A—C (1—3) were isolated from the black heartwood of Cryptomeria japonica. The structure of sugikurojin A was deduced to be 19-hydroxy-6,7-dehydroferruginol on the basis of extensive NMR experiments. Sugikurojin B was a dimer of 6,7-dihydroxyferruginol and 6,7-dehydroferruginol with a 6-O-11′ linkage. Sugikurojin C was a dimeric ferruginol with 6-O-7′ and 7-O-6′ linkages. Also obtained in this investigation were the known compounds formosaninol (4), 15 sesquiterpenes (5—19), 16 diterpenes (20—35), three phenylpropanoids (36—38), and a phenolic compound (39).