Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
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Epoxidation with an Electrocatalytic P-450 Model System in an Acidic Solution
Takashi MichidaChika SaikiChie YamasakiYumiko Yamaoka
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2005 年 53 巻 2 号 p. 151-152

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An electrochemical P-450 model system using meso-tetraphenylporphyrinatomanganese(III) chloride (MnTPP), imidazole and acetic acid was tested in an acetonitrile solution, and epoxide was obtained with a good current efficiency. The results of cyclic voltammetry revealed that acid plays an important role in the second electron transfer.
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© 2005 The Pharmaceutical Society of Japan
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