Absolute Ordered Cluster Formation of an o-Bisguanidinobenzene–Benzoic Acid Complexes

Masatoshi Kawahata; Kazuaki Shikii; Hiroko Seki; Tsutomu Ishikawa; Kentaro Yamaguchi

doi:10.1248/cpb.54.147

Communications to the Editor

Absolute Ordered Cluster Formation of an o-Bisguanidinobenzene–Benzoic Acid Complexes

Masatoshi Kawahata, Kazuaki Shikii, Hiroko Seki, Tsutomu Ishikawa, Kentaro Yamaguchi

著者情報

キーワード: guanidine chemistry, acid-base system, cluster, cold-spray ionization mass spectrometry, pulsed field gradient NMR

ジャーナルフリー

2006 年 54 巻 1 号 p. 147-148

DOI https://doi.org/10.1248/cpb.54.147

詳細

抄録

Stoichiometry-controlled complexation of o-phenylenebis-(N,N′-dimethyl-N,N′-ethylene)guanidine (BG) and benzoic acid (BA), which is forming 1 : 1, 1 : 2, 1 : 3, and 1 : 4 BG+BA systems, was observed in solution by using cold-spray ionization mass spectrometry CSI-MS and pulsed field gradient PFG NMR diffusion and in the solid state by X-ray structure analysis.

責任著者(Corresponding author)

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