Synthesis of Marine Diterpene Isocyanide (−)-Kalihinol Y and Diterpene Isothiocyanate (−)-10-Epi-kalihinol I

Hiroaki Miyaoka; Yasunori Abe; Etsuko Kawashima

doi:10.1248/cpb.c12-00485

Notes

Synthesis of Marine Diterpene Isocyanide (−)-Kalihinol Y and Diterpene Isothiocyanate (−)-10-Epi-kalihinol I

Hiroaki Miyaoka, Yasunori Abe, Etsuko Kawashima

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Keywords: diterpene isocyanide, diterpene isothiocyanate, synthesis, kalihinol Y, 10-epi-kalihinol I

JOURNAL FREE ACCESS

2012 Volume 60 Issue 9 Pages 1224-1226

DOI https://doi.org/10.1248/cpb.c12-00485

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Abstract

The authors described the first synthesis of diterpene isocyanide (−)-kalihinol Y and diterpene isothiocyanate (−)-10-epi-kalihinol I from synthetic intermediates of kalihinol A. The absolute structures of these compounds were confirmed by these syntheses.

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