Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Special Collection of Papers: Regular Articles
Glycosylation Reaction of Thioglycosides by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter
Tetsuya KajimotoKoji MorimotoRyosuke OgawaToshifumi DohiYasuyuki Kita
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2016 Volume 64 Issue 7 Pages 838-844

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Abstract

Thioglycosides are available donors in glycosylation due to the stability of the anomeric C–S bond under general reaction conditions of protection and deprotection, and offer orthogonality in their activation. We report now that the hypervalent iodine effectively induced glycosylation reaction of thioglycosides with various alcohols. This method features a high efficiency, completion in a short time, and proceeding under very mild conditions.

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© 2016 The Pharmaceutical Society of Japan
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