Development of a Sulfur-Modified Glass-Supported Pd Nanoparticle Catalyst for Suzuki–Miyaura Coupling

Mincen Xiao; Naoyuki Hoshiya; Katsumasa Fujiki; Tetsuo Honma; Yusuke Tamenori; Satoshi Shuto; Hiromichi Fujioka; Mitsuhiro Arisawa

doi:10.1248/cpb.c16-00261

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Development of a Sulfur-Modified Glass-Supported Pd Nanoparticle Catalyst for Suzuki–Miyaura Coupling

Mincen Xiao, Naoyuki Hoshiya, Katsumasa Fujiki, Tetsuo Honma, Yusuke Tamenori, Satoshi Shuto, Hiromichi Fujioka, Mitsuhiro Arisawa

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Keywords: nanoparticle, palladium, cross-coupling

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Supplementary material

2016 Volume 64 Issue 8 Pages 1154-1160

DOI https://doi.org/10.1248/cpb.c16-00261

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Abstract

A safe, facile and low-leaching (up to 0.17 ppm) sulfur-modified glass-supported palladium nanoparticle catalyst has been developed for the Suzuki–Miyaura coupling of aryl halides with aryl boronic acids. Most notably, this catalyst was highly recyclable and could be used up to 10 times without any discernible decrease in its activity.

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