Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Communications to the Editor
Chiral Organocatalyzed Intermolecular Rauhut–Currier Reaction of Nitroalkenes with Ethyl Allenoate
Shinobu TakizawaMakoto SakoKenta KishiMasashi ShigenobuGiang Vo-ThanhHiroaki Sasai
Author information
JOURNALS FREE ACCESS FULL-TEXT HTML

2017 Volume 65 Issue 11 Pages 997-999

Details
Abstract

An enantioselective intermolecular Rauhut–Currier (RC) reaction of nitroalkenes with ethyl allenoate has been established with quinidine-derived β-isocupreidine. The present RC reaction afforded α-functionalized allenoates 3 in up to 94% yield with 59% enantiomeric excess (ee).

Graphical Abstract Fullsize Image
Information related to the author
© 2017 The Pharmaceutical Society of Japan
Next article
feedback
Top