Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Acetylenic Compounds. XXXIV. Rearrangement of Propargylammonium Halide Derivatives.
岩井 一成平岡 哲夫
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1963 年 11 巻 12 号 p. 1556-1563

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The Stevens type rearrangement of phenylpropargylammonium halide derivatives was carried out. This rearrangement usually consists of 1, 2-shift of migratory group, however, it was found that bis phenylpropargylammonium halide derivative underwent the 1, 4-shift to give an allenic compound. The rearrangement was extended to a ring expansion reaction.
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© The Pharmaceutical Society of Japan
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