Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
An Approach to Synthesis of Diterpenoid Alkaloids. II.
清水 文治小木曾 彰岩井 一成
著者情報
ジャーナル フリー

1963 年 11 巻 6 号 p. 766-769

詳細
抄録
Cyclyzation of 3-methyl-9-(p-methoxyphenethyl)-3-azabicyclo [3. 3. 1] nonan-9-ol (Va : R=H) with polyphospholic acid gave a spiro compound of azabicyclononane (VI), but not a hydrophenanthrene derivative (VI'). The evidence for the structure of the cyclization product was provided by the fact that on oxidation with chromic acid, VI gave the 1-indanone (IX) showing the infrared absorption at 1706 cm-1 and the lactam ketone (X) showing the absorptions at 1705 cm-1 and 1600 cm-1.
著者関連情報
© The Pharmaceutical Society of Japan
前の記事 次の記事
feedback
Top