Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Photochemical Reaction of Ubiquinone (35). IV. Formation of Demethylubiquinone (35)
Isuke ImadaYasushi SannoHiroshi Morimoto
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1964 Volume 12 Issue 9 Pages 1056-1059

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Abstract
It was made clear that one of the photochemical reaction produts of ubiquinone (35) (I) had the structure (II) in which one of the two methoxyls of I was converted to a hydroxyl. And it was named demethylubiquinone (35). II was converted to demethylubichromenol (35) (IV) by treating with triethylamine, and the position of the hydroxyls of II was decided from the fact that the two hydroxyls of IV gave a color reaction with phosphomolybdic acid, showing that they are in ortho-relation.
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© The Pharmaceutical Society of Japan
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