Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Synthesis of Tricholomic Acid. VIII. Synthesis of Diastereoisomers of Isotricholomic Acid from β-Hydroxyglutamic Acid γ-Esters
TAKAAKI KAMIYA
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1969 Volume 17 Issue 5 Pages 895-900

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Abstract
Two diastereoisomers of isotricholomic acid (II), structural isomers of tricholomic acid (erythro-L-I) were synthesized from the corresponding diastereoisomers of β-hydroxyglutamic acid γ-ester (V) by the method for the synthesis of I. During the synthesis of II, the diastereoisomers of I were obtained by a novel intramolecular rearrangement.
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© The Pharmaceutical Society of Japan
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