Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
The Reaction of α, β-Unsaturated Ketones with Azides. III.
三橋 監物野村 敬一南 法夫松山 稔
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1969 年 17 巻 8 号 p. 1578-1584

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The reaction of seven kinds of conjugated bicycloalkenones (I, III, V, VII, IX, XV and XX) with hydrazoic acid were studied. From compounds (I, III, V and VII), enone type lactams were obtained and from compounds (IX, XV and XX), α, β-unstaturated α-aminoketones were obtained. The three types of reaction products (a) lactams, b) α, β-unsaturated α-aminoketones and c) β-diketones) were observed from present and previous results. The correlation between the structure of α, β-unsaturated ketone and the reaction product was discussed.
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© The Pharmaceutical Society of Japan
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