Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Mesoionic Compounds. I. Synthesis of 3-Dialkylaminosydnonimines
KATSUTADA MASUDAYOSHIO IMASHIROTATSUHIKO KANEKO
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1970 Volume 18 Issue 1 Pages 128-132

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Abstract
3-Dialkylaminosydnonimine salts (IV) were synthesized starting from 1, 1-dialkyl-hydrazines (I) via II and III. IV exhibits a remarkable stability towards acids and could be obtained as crystals. Chemical and physicochemical properties of IV were similar to those of known sydnonimine salts. It should be mentioned that intermediary nitroso compounds (III) were rather unstable and spontaneously gave rise to unsaturated nitriles (III').
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© The Pharmaceutical Society of Japan
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