Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Preparation of Resonance-Stabilized Bisphosphoranes
HARUO SAIKACHIHIROSHI MUTO
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1971 Volume 19 Issue 11 Pages 2262-2270

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Abstract
Five resonance-stabilized bisphosphoranes were prepared for the object of the future work. Preliminary examination was carried out in order to make clear the reactivity of the resonance-stabilized bisphosphoranes with the six aromatic monoaldehydes by the Wittig reaction. An unexpected ester exchange reaction of ethyleneglycol bischloroacetate (1) was discussed in the case of 9, 6-dioxa-2, 7-dioxoheptane-1, 8-bistriphenylphosphonium chloride formation.
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© The Pharmaceutical Society of Japan
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