Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Formic Acid Reduction. XVIII. Formic Acid Reaction of p-(Dialkylamino) azobenzenes
MINORU SEKIYAOSAMU MATSUDAJIRO SUZUKIMASAYASU TOMIE
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1973 年 21 巻 2 号 p. 372-382

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It has been found that p-(dialkylamino) azobenzenes undergo a novel reaction on heating with formic acid or the constant boiling liquid formate composed of formicacid and trialkylamine. The reaction involves a number of reaction stages such as reduction, bond fission and migration, giving a number of the products, N-alkyl and N-formyl derivatives of p-phenylenediamine and of aniline.
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© The Pharmaceutical Society of Japan
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