Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Enduracidin, a New Antibiotic. VIII. Structures of Enduracidins A and B
岩崎 英介, 堀井 聡, 浅井 満子, 水野 公明, 上柳 次三郎, 三宅 彰
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1973 年 21 巻 6 号 p. 1184-1191

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From the structural investigation of acidic products obtained by hydrolysis of enduracidins and tetrahydroenduracidins, 10-methylundeca-2 (cis)-4 (trans)-dienoic acid (V) and (+)-10-methyldodeca-2 (cis)-4 (trans)-dienoic acid (VI) were found to be constituent of enduracidins A and B, respectively. Consequently, the structural difference between enduracidins A and B was proved to be present in their unsaturated fatty acid moieties, and their full structures were assumed to be as shown in Fig. 10.
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© The Pharmaceutical Society of Japan
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