Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Reaction of N-Haloamide. XVIII. Oxidation of Ether to Ester with N-Haloamide
YOSHIKO KAMIYASHOJI TAKEMURA
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1973 Volume 21 Issue 7 Pages 1401-1403

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Abstract
The oxidation of tetrahydrofuran, tetrahydropyran or n-butyl ether with N, N-dibromobenzenesulfonamide (DBBS) in the presence of water gave γ-butyrolactone, δ-valerolactone or n-butylbutyrate, respectively (Table I). The mechanism of reaction was discussed in connection with the reaction of tetrahydrofuran with DBBS in nonaqueous solvent.
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© The Pharmaceutical Society of Japan
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