Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Reaction of N-Haloamide. XIX. Reaction of Acetals with N, N-Dibromobenzenesulfonamide
神谷 佳子竹村 庄司
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1974 年 22 巻 1 号 p. 201-206

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Some oxidative cleavages of acetals with N, N-dibromobenzenesulfonamide (DBBS) have been presented. As a result of oxidative fission of C-O bond and simultaneous bromination, these reaction gave ester and alkyl bromide, or brominated esters (shown in Table I). The reaction mechanism has been discussed on the basis of the experiments and the previous investigation on the reaction of ethers with DBBS.
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© The Pharmaceutical Society of Japan
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