Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
On the Constituents of the Lichen in the Genus Menegazzia. Menegazziaic Acid, a New Depsidone from Menegazzia asahinae (YAS. ex ZAHLBR.) SANT. and Menegazzia terebrata (HOFFM.) MASS
平山 晃久藤川 雅司吉岡 一郎北川 勲
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1976 年 24 巻 10 号 p. 2340-2344

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Following the thin-layer chromatographic examinations of the acetone extractive of two lichens : Manegazzia asahinae (YAS. ex ZAHLBR.) SANT. and M. terebrata (HOFFM.) Mass, which have been disclosed to contain the same kinds of metabolites, a new depsidone named menegazziaic acid (4) has been isolated from M. terebrata in addition to stictic acid (1), atranorin (2), constictic acid (3), and chloroatranorin (5) The structure of menegazziaic acid has been established as 4, in which the formyl function at C-3 of stictic acid (1) is replaced by a hydroxyl, on the basis of chemical and physicochemical evidence including the chemical conversion of menegazziaic acid to stictic acid (1).
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© The Pharmaceutical Society of Japan
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