Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Plant Mucilages. XIV. Isolation and Characterization of a Mucous Polysaccharide, "Lilium-La-glucomannan" from the Bulbs of Lilium lancifolium
友田 正司金子 幸子大森 千英子潮崎 智子
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1976 年 24 巻 11 号 p. 2744-2750

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A mucous polysaccharide, named Lilium-La-glucomannan, has been isolated from the bulbs of Lilium lancifolium THUNB. It was homogeneous on glass-fiber paper electrophoresis and by ultra centrifugal analysis. The component sugars of it were D-mannose and D-glucose in the molar ratio of 5 : 2, and its molecular weight was measured at 417000. The O-acetyl groups in the polysaccharide were identified and determined as the content of 1.2%. They are located in positions 2, 3, and 6 of a part of D-mannose units. Methylation, periodate oxidation and partial acetolysis studies suggested that the polysaccharide is mainly composed of β-1→4 linked aldohexopyranose residues and it contains about thirty aldohexose units per one end group on the average. D-Mannose units occupy non-redncing terminal positions and branch points linked through positions 2 and 3.
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© The Pharmaceutical Society of Japan
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