Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Carbon-13 Magnetic Resonance Spectroscopy. VIII. Stereochemistry of Quinolizidines (1)
MAKIKO SUGIURAYOSHIO SASAKI
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1976 Volume 24 Issue 12 Pages 2988-2994

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Abstract
The C-13 magnetic resonance chemical shifts of quinolizidine and cis-and trans-4-methylquinolizidine were examined. The correlations between the stereochemistry of these compounds and results on their C-13 chemical shifts and protonation and quaternization effects were examined. trans-4-methylquinolizidine was concluded to have a trans-fused ring and an axial methyl proup. The C-H coupling constants of those compounds were also examined.
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© The Pharmaceutical Society of Japan
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