Abstract
The reaction of anti-oxime (1) of 2-phenoxycyclohexanone was attempted in continuation of the former studies on the Grignard reactions of oximes. Consequently, it ended in a result entirely different from the Hoch-Campbell reaction and also the intramolecular ringclosure reaction which has been previously reported. causing the elimination of phenol and the productions of aniline and 2-phenoxycyclohexanone in main. The reaction pathway was discussed. Additionally, the government of reaction by both changes of 2-substituent on cyclohexanone oxime and Grignard reagent was preliminarily examined.
