Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Halogenation Reaction of Bis (acetylacetonato) nickel (II) and-cobalt (II) Chelate
KOJI YAMAKAWAHAJIME KANEOYA
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1976 Volume 24 Issue 8 Pages 1931-1934

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Abstract
Introduction of chlorine, bromine, and iodine atom into the ring of labile bivalent metal acetylacetonates, bis (acetylacetonato) nickel (II) and-cobalt (II) chelates, is effected by N-halosuccinimide in carbon tetrachloride. Infrared and ultraviolet spectra of halogenated metal (II)-acetylacetonate chelate derivatives were measured. The masses of substituent at the central carbon atom of these metal (II)-acetylacetonates affected the frequencies of C=O and C=C stretching bands.
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© The Pharmaceutical Society of Japan
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