Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Diterpenoids. XLV. Ozonolysis of Phenolic Dehydroabietic Acid Derivatives
秋田 弘幸森 和彦田原 昭
著者情報
キーワード: sesquiterpenoid
ジャーナル フリー

1977 年 25 巻 5 号 p. 974-980

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抄録
Ozonolysis of phenolic dehydroabietic acid derivatives with an isopropyl group at 13-position was investigated and the direction of cleavage of the aromatic ring by means of ozonolysis was found to be affected by the substitution pattern of hydroxyl group in the aromatic ring. Ozonolysis of the 12-hydroxy ester (12) afforded the pentanorlabdane type compounds, (13), (14), and (15), while ozonolysis of the 14-hydroxy ester (17) and (18) gave the drimane type products, (19) and (20).
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© The Pharmaceutical Society of Japan
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