Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Lupin Alkaloids. VIII. A New Stereoisomer of Sophocarpine
森永 邦夫上野 明福島 清吾浪越 通夫飯高 洋一奥田 重信
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1978 年 26 巻 8 号 p. 2483-2488

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A new stereoisomer (I) of (-)-sophocarpine (II) was isolated from epigeal part of Sophora flavescens. The relative configuration and stereochemistry were determined by X-ray diffraction studies with monohydrate of free base. The absolute configuration was elucidated by chemical interrelation of I with (+)-matrine (III) and (+)-allomatrine (IV) of known absolute configuration.
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© The Pharmaceutical Society of Japan
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