Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Synthesis of Norbornene Anhydride-Mercury Compound and Its Nucleophilic Reaction
TERUO TAKAHASHI
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1979 Volume 27 Issue 4 Pages 870-873

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Abstract
5-Norbornene anhydride-mercury compound (III) was synthesized. Since its infrared spectrum showed the shift of carbonyl absorption to a very low wave number side, O-Hg linkage was considered to be in an ionic form (III'), with the carbon in the bonded to mercury becoming a carbonium ion, suggesting the likelihood of its reaction with nucleophilic reagents. Reactions of III with nucleophilic reagents showed that III is reactive to H2S, KI, and KCN.
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© The Pharmaceutical Society of Japan
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