Phosphorylation of Alcohols via Anodic P-Halogenation of Dialkyl Hydrogen Phosphites
キーワード:
trialkyl phosphates
1979 年 27 巻 7 号 p. 1700-1703
詳細
1979 年 27 巻 7 号 p. 1700-1703
Trialkylphosphates, (RO)2P(O)OR', were prepared from dialkyl hydrogen phosphites, (RO)2PHO, and lithium chloride in R'OH by constant current electrolysis at a glassy carbon anode. Electrolysis at an anode having a larger area and at a lower current density gives better yields of the products. The electrolytic phosphorylation was also performed in acetone and in acetonitrile.
