Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Activation of N-Hydroxy Compounds by P-O Bond Formation through Anodic Oxidation of Triphenylphosphine
HIDENOBU OHMORISHIRO NAKAIMASAICHIRO MASUI
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Keywords: phosphonium ions
JOURNAL FREE ACCESS

1980 Volume 28 Issue 7 Pages 2247-2250

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Abstract
Controlled potential electrolyses of triphenylphosphine (TPP) in acetonitrile containing an excess of N-hydroxy compounds such as ketoximes, aldoximes, and hydroxamic acids were examined : subsequent treatment of the products under mild conditions gave amides, nitriles, and ureas, respectively. Electrolyses under conditions where the amounts of TPP were equal to or larger than those of the N-hydroxy compounds did not give satisfactory results.
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© The Pharmaceutical Society of Japan
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