Studies on the Syntheses of Heterocyclic Compounds. DCCCXCII. An Efficient Stereoselective Synthesis of Potential Intermediates for Rauwolfia Alkaloids from Furan and Its Derivatives

TOSHIO SUZUKI; AKIKO TOMINO; KATSUO UNNO; TETSUJI KAMETANI

doi:10.1248/cpb.29.76

TOSHIO SUZUKI, AKIKO TOMINO, KATSUO UNNO, TETSUJI KAMETANI

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Keywords: synthesis of 3, 8-epoxy-4-halo-7-oxo-2-alkoxycarbonylmethyl-6-oxabicyclo [3. 2. 1] octanes

JOURNAL FREE ACCESS

1981 Volume 29 Issue 1 Pages 76-81

DOI https://doi.org/10.1248/cpb.29.76

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Abstract

A general method for the stereoselective synthesis of the potential intermediates (11), (12), (20), and (21) for the Rauwolfia alkaloid reserpine (1) and its analogs starting from furan and benzyl furfuryl ether is described.

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