Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Relationship between the Color Transition and the Equivalence Point of Methylrosaniline Chloride in Non-aqueous Titration
SHIGERU YOSHIDAKAYOKO ODASHINGO HIROSE
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1981 Volume 29 Issue 6 Pages 1662-1669

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Abstract
The determination of some weak bases at low concentrations was investigated photometrically in non-aqueous solvents. To ensure accuracy, the chemical stoichiometric relationship between color transition of the indicator and the equivalence point was considered. The color transition of the indicator was calculated by complementary tristimulus colorimetry, which is preferable to ordinary colorimetry when dealing with several species in solution. Theoretical titration curves of titration ratio versus color transition were drawn and compared with the experimental data. It was found that 10-2 M-10-4 M sample solution could be determined in non-aqueous solvents.
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© The Pharmaceutical Society of Japan
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