Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Flash Vacuum Pyrolysis of Aromatic Oximes
AKIO OHSAWA, TAKAYUKI KAWAGUCHI, HIROSHI IGETA
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Keywords: mass spectra
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1982 Volume 30 Issue 12 Pages 4352-4358

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Abstract
Flash vacuum pyrolysis (FVP) of benzaldoximes and aryl ketoximes afforded nitriles and additional aromatic compounds which were presumably generated from intermediary iminyl radicals. The FVP also gave benzoxazoles, which were presumably formed from iminoxyl radicals. Benzyl ketoximes afforded indoles together with fragmentation products of the iminyl radicals.
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© The Pharmaceutical Society of Japan
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