Thermal Rearrangements of Allyl 2, 2-Dichloro-, 1, 2-Dichloro- and 1, 2, 2-Trichloro-substituted Vinyl Sulfides

Abstract

Thermal rearrangements of allyl perchlorovinyl sulfides, such as 2, 2-dichloro-, 1, 2-dichloro- and 1, 2, 2-trichloro-substituted vinyl sulfides, are shown to involve unique rearrangements of the carbon skeletons with migration of the chlorines.