Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Umpolung of Reactivity of Allylsilane, Allylgermane, and Allylstannane via Their Reaction with Thallium (III) Salt : A New Allylation Reaction for Aromatic Compounds
落合 正仁藤田 栄一有本 正生山口 秀夫
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キーワード: umpolung
ジャーナル フリー

1983 年 31 巻 1 号 p. 86-93

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抄録
A new direct allylation of aromatic compounds has been developed. A mixture of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate was allowed to react with an aromatic compound, a nucleophile, to give allylation product (s) in good yields via an allylcationic species. Thus, the usefulness of these allylmetal compounds as allyl cation equivalents was established.
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© The Pharmaceutical Society of Japan
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