Abstract
1, 2, 3-Triazine 2-imine reacted with dimethyl acetylenedicarboxylate to give adducts of a novel type (2, 3-bis (carbomethoxy) -8, 8a-dihydropyrazolo[2, 3-b][1, 2, 4]triazines) which were considered to be formed from the primary 1, 3-dipolar cycloadducts via a ring transformation.