Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
A New Aromatic Annelation Reaction with Two Synthons, Enaminones and 3-Oxoglutarate. Studies on the β-Carbonyl Compounds Connected with β-Polyketides. VIII
NAOKI TAKEUCHI, NAOMI OKADA, SEISHO TOBINAGA
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Keywords: dimethyl 2-hydroxy-1, 3-benzenedicarboxylate
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1983 Volume 31 Issue 12 Pages 4355-4359

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Abstract
Reactions of the enaminones 1 with dimethyl 3-oxoglutarate in the presence of KF-AcOH or AcONa-AcOH and 18-crown-6 gave the dimethyl 2-hydroxy-1, 3-benzenedicarboxylates 3, providing a new aromatic annelation reaction.
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© The Pharmaceutical Society of Japan
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