Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Free Sterols of the Sea Urchin Echinometra lucunter
CARMENZA DUQUEALVARO BERNALROSALBELde CORREAMASUO MORISAKINOBUO IKEKAWA
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Keywords: Echinoid
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1983 Volume 31 Issue 4 Pages 1366-1369

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Abstract
The sterol components of the Colombian sea urchin Echinometra lucunter were fractionated by high performance liquid chromatography (HPLC) and analyzed by gas chromatography-mass spectrometry (GC-MS) and 360 MHZ proton magnetic resonance (1H-NMR) spectroscopy. The sea urchin contains mainly Δ5-C27 sterols with cholesterol as the main constituent. Various Δ5-C26, -C28, and -C29 sterols were also found. This is the first report of the presence of 24§-27-nor-24-methylcholesta-5, 22-dien-3β-ol (2), (22E, 24S)-24-methylcholesta-5, 22-dien-3β-ol (6), 24-methylcholesta-5, 24-dien-3β-ol (7) and 5α-cholestan-3β-ol (13) in sea urchin.
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© The Pharmaceutical Society of Japan
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