Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
THE TRANSFORMATION OF MESACONITINE TO ISODELPHININE : DEOXYGENATION OF BRIDGEHEAD HYDROXYL
Takao MoriHideo BandoYoshio KanaiwaKoji WadaRiho SatoTakashi Amiya
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Keywords: photolysis
JOURNAL FREE ACCESS

1983 Volume 31 Issue 4 Pages 1422-1423

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Abstract
A trifluoromethanesulfonate of anhydromesaconitine was subjected to photochemical reaction, which contains replacement of the bridgehead hydroxyl at C (13) by hydrogen, followed by catalytic hydrogenation, yielding isodelphinine.
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© The Pharmaceutical Society of Japan
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