Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Anodic Oxidation of Pyrones and Coumarins
西山 敦子衛藤 英男井口 正信山村 庄亮
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キーワード: cyanation
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1983 年 31 巻 8 号 p. 2853-2858

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抄録
Triacetic lactone, 4-hydroxycoumarins and 2-chloromethyl-5-hydroxy-4-pyrone were subjected to anodic oxidation in methanol containing LiClO4 or NaCN to afford the corresponding methoxy or cyano compounds. In basic media, however, bispyrone and biscoumarol were produced from triacetic lactone (4-hydroxy-6-methyl-2-pyrone) and 4-hydroxycoumarin, respectively. The formation processes of these oxidation products are discussed.
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© The Pharmaceutical Society of Japan
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