NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 37. TRIMETHYLSILYLDIAZOMETHANE, A CONVENIENT REAGENT FOR THE PREPARATION OF VINYLSILANES FROM ALKANESULFONYL CHLORIDES

Toyohiko Aoyama; Sachio Toyama; Naoko Tamaki; Takayuki Shioiri

doi:10.1248/cpb.31.2957

Chemical and Pharmaceutical Bulletin

Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363

NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 37. TRIMETHYLSILYLDIAZOMETHANE, A CONVENIENT REAGENT FOR THE PREPARATION OF VINYLSILANES FROM ALKANESULFONYL CHLORIDES

青山豊彦, 外山幸雄, 玉木直子, 塩入孝之

著者情報

キーワード: episulfone

ジャーナルフリー

1983 年 31 巻 8 号 p. 2957-2959

DOI https://doi.org/10.1248/cpb.31.2957

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抄録

Trimethylsilyldiazomethane reacts smoothly with alkanesulfonyl chlorides in the presence of triethylamine to give vinylsilanes.

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