Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Plant Constituents Biologically Active to Insects. IV. Antifeedants for the Larvae of the Yellow Butterfly, Eurema hecabe mandarina, in Arachniodes standishii
沼田 敦勝野 孝子山本 恭子西田 知子竹村 鶴子瀬戸 剛
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キーワード: Aspidiaceae
ジャーナル フリー

1984 年 32 巻 1 号 p. 325-331

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Nine species of plants having antifeeding activities for the larvae of the yellow butterfly, Eurema hecabe mandarina DE L'ORZA, were found. From one of them, Arachniodes standishii (MOORE) OHWI, the known compound, 1-(2, 4, 6-trimethoxyphenyl) but-trans-2-en-1-one (I), was isolated as an antifeedant. This compound was synthesized according to the Friedel-Crafts procedure, which also gave two new compounds, 1, 3-bis (2, 4, 6-trimethoxyphenyl) butan-1-one (VI) and 1-(2, 4, 6-trimethoxyphenyl)-3-[3-(2-trans-butenoyl)-2, 4, 6-trimethoxyphenyl] butan-1-one (VII), as by-products. Treatment of 1, 3, 5-trimethoxybenzene (V) with ferric chloride was found to afford 2, 2', 4, 4', 6, 6'-hexamethoxybiphenyl (VIII), which has been synthesized according to Ullmann's procedure.
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© The Pharmaceutical Society of Japan
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