STEREOSELECTIVE ALDOL REACTION OF A LITHIUM α-VINYL ENOLATE TO α-ALKOXY ALDEHYDES
1984 年 32 巻 1 号 p. 373-376
詳細
1984 年 32 巻 1 号 p. 373-376
Stereoselective synthesis of the 4, 5-syn, 5, 6-anti adducts (14 and 16) on the aldol condensation of the Z (O)-lithium enolate, derived from the E-enone (2), to α-alkoxy aldehydes (12 and 13) was proved via the successive intramolecular Diels-Alder reaction.
