Synthesis of 2- (5-Cholesten-3β-yloxy) Glycosides of N-Acetyl-D-neuraminic Acid Derivatives

SHINGO SATO; SYUJI FUJITA; KIMIO FURUHATA; HARUO OGURA; SHOJI YOSHIMURA; MASAYOSHI ITOH; YOSHIYASU SHITORI

doi:10.1248/cpb.35.4043

SHINGO SATO, SYUJI FUJITA, KIMIO FURUHATA, HARUO OGURA, SHOJI YOSHIMURA, MASAYOSHI ITOH, YOSHIYASU SHITORI

著者情報

キーワード: N-acetylneuraminic acid, Ο-glycoside, cholesterol, NMR, CD, stereochemistry

ジャーナルフリー

1987 年 35 巻 10 号 p. 4043-4048

DOI https://doi.org/10.1248/cpb.35.4043

詳細

抄録

2-(5-Cholesten-3β-yloxy)α- and β-glycosides of N-acetyl-D-neuraminic acid were prepared under various conditions through a Koenigs-Knorr-like reaction. The stereochemistry of the products was confirmed by analysis of the nuclear magnetic resonance and circular dichroism spectra.

責任著者(Corresponding author)

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