One-Step Preparation of 1-Alkenyltriphenylphosphonium Perchlorates by Electrochemical Oxidation of Triphenylphosphine in the Presence of Alkenes

HIDENOBU OHMORI; TOSHIKATSU TAKANAMI; MASAICHIRO MASUI

doi:10.1248/cpb.35.4960

HIDENOBU OHMORI, TOSHIKATSU TAKANAMI, MASAICHIRO MASUI

著者情報

キーワード: triphenylphosphine, 1-alkenyltriphenylphosphonium perchlorate, alkene, electrochemical oxidation, constant current electrolysis

ジャーナルフリー

1987 年 35 巻 12 号 p. 4960-4963

DOI https://doi.org/10.1248/cpb.35.4960

詳細

抄録

Electrochemical oxidation of triphenylphosphine in dichloromethane at a graphite anode in the presence of olefins has been shown to be a convenient method for the preparation of 1-alkenyltriphenylphosphonium perchlorates under mild conditions.

責任著者(Corresponding author)

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