Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Preparation of a Tricyclic A-Ring Analog of Quassin
YOHEI KURATAHIROSHI HIROTATADASHI HONDATAKEYOSHI TAKAHASHI
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JOURNAL FREE ACCESS

1987 Volume 35 Issue 2 Pages 837-840

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Abstract
(±) -3-Methoxy-1α, 4aβ, 8aβ-trimethyl-1, 4, 4a, 6, 7, 8, 8a, 9, 10, 10a α-decahydrophenanthrene-4, 8-dione, a tricyclic A-ring analog of quassin, was synthesized from a known tricyclic ketone through seven reaction steps, including phenylselenation in a neutral medium and the Wharton reaction.
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© The Pharmaceutical Society of Japan
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