Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Evidence for Ambivalent Azomethine Ylide Intermediate in the 1, 3-Cycloaddition of Trimethylsilylmethyla mine Derivatives
YOSHIYASU TERAO, NOBUYUKI IMAI, KAZUO ACHIWA
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Keywords: azomethine ylide, 1, 3-cycloaddition, ambivalence, N-benzyl-N- (methoxymethyl) trimethylsilylmethylamine, tetrabutylammonium fluoride
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1987 Volume 35 Issue 4 Pages 1596-1598

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Abstract

Evidence for an ambivalent azomethine ylide intermediate was provided by the 1, 3-cycloaddition of deuterated N-benzyl-N- (methoxymethyl) trimethylsilylmethylamine to dimethyl benzylidene malonate and related reactions.

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