Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Intramolecular Photoreactions of Phthalimide-Alkene Systems. Oxetane Formation of N-(ω-Indol-3-ylalkyl)phthalimides
HARUKO TAKECHI, MINORU MACHIDA, YUICHI KANAOKA
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Keywords: photoreaction
JOURNAL FREE ACCESS

1988 Volume 36 Issue 8 Pages 2853-2863

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Abstract
Upon irradiation in acetone, N-(ω-indol-3-ylalkyl)phthalimides (1, n=2-5) underwent intramolecular Paterno-Buchi reaction to give oxeto[2, 3-b]indoles or their ring-opening products. However, N-(ω-indol-2-ylalkyl)phthalimides (9, n=2, 3) yielded not the oxetane, but the N-deacetylated compounds.
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© The Pharmaceutical Society of Japan
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